Q1: I used this card's When Digivolving effect to reduce the DP of an opponent's Digimon to 0, then I played EX8-062 Piedmon ACE. Does that EX8-062 Piedmon ACE's All Turns effect trigger at such times?
Yes, it triggers. Even if you use this card's When Digivolving effect to reduce the DP of an opponent's Digimon to 0, it isn't yet deleted at that time. After you play EX8-062 Piedmon ACE from your trash and this effect is resolved, then all Digimon with 0 DP are deleted at the same timing. Digimon with a DP of 0 are deleted after playing EX8-062 Piedmon ACE, then EX8-062 Piedmon ACE's All Turns effect will trigger.
Lv.7 Boltboutamon EX8-064 SR Mega | Virus | Wizard/NSo [DNA Digivolve] [Piedmon] + [Myotismon]: Cost 0 [When Digivolving] <De-Digivolve 3> 1 of your opponent's Digimon and, for the turn, all of their Digimon get -6000 DP. Then, if DNA digivolving, you may play up to 10 play cost's total worth of [NSo] trait Digimon cards from your trash without paying the cost. [All Turns] [Once Per Turn] When other Digimon are deleted, trash your opponent's top security card.
Lv.7 Boltboutamon EX8-064 SR Mega | Virus | Wizard/NSo [DNA Digivolve] [Piedmon] + [Myotismon]: Cost 0 [When Digivolving] <De-Digivolve 3> 1 of your opponent's Digimon and, for the turn, all of their Digimon get -6000 DP. Then, if DNA digivolving, you may play up to 10 play cost's total worth of [NSo] trait Digimon cards from your trash without paying the cost. [All Turns] [Once Per Turn] When other Digimon are deleted, trash your opponent's top security card.
Lv.7 Boltboutamon EX8-064 SR Mega | Virus | Wizard/NSo undefined/[DNA Digivolve] [Piedmon]+[Myotismon]: Cost 0 [When Digivolving] <De-Digivolve 3> 1 of your opponent's Digimon and, for the turn, all of their Digimon get -6000 DP. Then, if DNA digivolving, you may play 10 play cost's total worth of [NSo] trait Digimon cards from your trash without paying the cost. [All Turns] [Once Per Turn] When other Digimon are deleted, trash your opponent's top security card.
Lv.7 ボルトバウタモン EX8-064 SR 究極体 | ウィルス種 | 魔人型/NSo 〔ジョグレス〕「ピエモン」+「ヴァンデモン」:コスト0 【進化時】相手のデジモン1体を≪退化3≫し、ターン終了まで、相手のデジモン全てをDP-6000。その後、ジョグレス進化していたなら、自分のトラッシュから、特徴に「NSo」を持つデジモンカードを登場コスト合計10まで、コストを支払わずに登場できる。 【お互いのターン】[ターンに1回]他のデジモンが消滅したとき、相手のセキュリティを上から1枚破棄する。